t-3-Ethyl-r-2,c-6-bis(2-furyl)piperidin-4-one

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1-Acetyl-t-3-ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)piperidin-4-one

In the title compound, C(23)H(27)NO(4), the piperidine ring adopts a distorted boat conformation. The meth-oxy groups lie in the plane of benzene rings to which they are attached [maximum deviations of 0.014 (3) and 0.007 (3) Å]. The benzene rings are oriented at angles of 67.2 (1) and 87.0 (1)° with respect to the best plane through the four co-planar atoms of the piperidine ring.

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t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one

In the title mol-ecule, C(21)H(24)N(2)O(4), the piperidine ring adopts a distorted boat conformation with the ethyl substituent in the axial position. The dihedral angle between the two benzene rings is 70.25 (9)°. An intra-molecular C-H⋯O inter-action is observed. In the crystal, mol-ecules are linked into a chain along the c axis by C-H⋯O hydrogen bonds and the chains are linked via weak C-H⋯...

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t-3-Ethyl-r-2,c-6-bis­(2-fur­yl)piperidin-4-one

In the title mol-ecule, C(15)H(17)NO(3), the piperidine ring adopts a chair conformation. The dihedral angle between the two furyl rings is 72.4 (1)°. The ethyl group and the furyl rings have equatorial orientations. Mol-ecules are linked by N-H⋯O hydrogen bonds.

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t-3-Pentyl-r-2,c-6-diphenyl­piperidin-4-one

In the title mol-ecule, C(22)H(27)NO, the piperidine ring adopts a chair conformation, with all substituents equatorial. The dihedral angle between the two phenyl rings is 56.90 (5)°. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds. A C-H⋯π inter-action involving the phenyl ring at the 6-position is also found in the crystal structure.

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Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate

In the title compound, C(21)H(19)BrO(3), the cyclo-hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 28.88 (10) and 71.94 (10)° with the bromo-benzene and phenyl rings, respectively. The dihedral angle between the latter two rings is 51.49 (15)°. Inter-molecular C-H⋯O hydrogen bonds are found in the ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2007

ISSN: 1600-5368

DOI: 10.1107/s1600536807062204